四川盆地广安地区中二叠统栖霞组岩石特征与沉积环境

四川盆地中二叠统栖霞组勘探发现系列油气，资源潜力巨大。但广安地区中二叠统栖霞组的岩石学特征及沉积环境研究薄弱。在野外地质调查的基础上，结合室内岩石学、岩相学等综合分析，对广安地区栖霞组碳酸盐岩岩石特征、沉积相类型及其古地理展布特征进行了系统研究。结果表明：广安地区栖霞组主要发育亮晶颗粒灰岩、亮晶生物碎屑灰岩、微晶生物碎屑灰岩、微晶颗粒灰岩、生物碎屑微晶灰岩、含生物碎屑微晶灰岩和泥晶灰岩7种岩石类型；碳酸盐岩颗粒主要以生物碎屑为主，部分层位发育球粒；古生物化石以三叶虫、腕足和有孔虫为主，同时可见棘皮类和藻类；栖霞组沉积期主要为碳酸盐岩台地沉积环境，其中栖霞组晚期（栖二段）台缘滩和台内滩较为发育，为该区油气成藏提供了有利条件。     

Spatial Distribution Assessment and Source Apportionment of Land-Based Pollutant Yield from Qingdao,China

The spatial distribution of chemical oxygen demand(COD) and total nitrogen(TN) yield from Qingdao are studied by comparing pollutant yield amount, densities and spatial aggregation(Getis-Ord indexes) among the land-based pollutant source regions(PSRs) entering the three sub-seas(i.e. the Jiaozhou Bay(JZB), other coastal area in the Yellow Sea(OCAYS) and Laizhou Bay(LZB), respectively). Industrial composition of the loads are also studied by comparing pollutant yield among the sources of agriculture, rural domesticity, industry, urban domesticity and service, and calculation of Gini coefficient. Results show that spatial distribution of COD and TN yield from Qingdao are extremely unbalanced. The JZB, with less than 3% of the total coastal sea area of Qingdao, received 62% COD load and 65% TN yield from Qingdao, while the OCAYS, with more than 97% area, only received 23% COD and 20% TN, which consist with the much worsen water quality of JZB than that of OCAYS. On the other hand, the source apportionment of COD and TN loads in the PSRs entering JZB and the OCAYS was similar. The agricultural and domestic sources with high pollution intensity account for more than 80%, while the industrial and service sources with low pollution intensity account for less than 20%. While Gini coefficients, COD 0.81 and TN 0.84 which are much higher than the ‘imbalance' threshold of 0.4, show the uneven industrial structure of Qingdao. These results may be useful in the determination of land-based pollution total amount control at the PSR level.     

帕米尔高原Rushan-Pshart古特提斯洋或中特提斯洋争论的岩石地球化学证据

帕米尔高原上广泛分布的加里东期火山岩,印支期火山岩与燕山期火山岩被认为是块体依次向北俯冲拼贴到欧亚板块上的产物。特别是燕山期火山岩被认为是Rushan-Pshart中特提斯洋闭合的产物。但近年来地层古生物、火山岩证据不断表明Rushan-Pshart洋闭合时间在晚三叠一早侏罗世,由此限定Rushan-Pshart古特提斯洋性质,而帕米尔高原上广泛分布的燕山期火山岩是更南部的Shyok中特提斯洋闭合的产物。目前,中国境内Rushan-Pshart缝合带属性的研究工作展开较晚,研究程度较低。我们对塔什库尔干明铁盖沟一线燕山期火山岩带展开的工作发现零星分布的印支期花岗岩。印支期花岗岩错石U・Pb年龄显示岩体侵位时间在201 Ma左右。全岩主量元素特征表明岩石为I型高钾钙碱性闪长花岗岩;稀土元素在球粒陨石标准化图解中呈轻稀土元素相对富集,重稀土元素相对亏损的右倾海鸥型。明铁盖岩体的微量元素显示大离子亲石元素明显富集,而高场强元素明显亏损。稀土微量元素特征倾向花岗岩属性为岛弧型花岗岩,Sr-Nd-Hf同位素比值特征显示岩体形成于下地壳部分熔融环境。岩体的地化特征表明岩体形成的构造环境为板块汇聚的洋壳俯冲阶段,结合区域地质特征,我们将花岗岩体归为Rushan-Pshart古特提斯洋壳俯冲消减的产物。Rushan-Pshart缝合带传统上认为是中特提斯带,近年的研究进展认为其为古特提斯缝合带,本文的工作支持这种观点。Rushan-Pshart古特提斯缝合带的确立对帕米尔高原与青藏高原主体的块体对比提供了可信的对比方案,并对青藏高原新生代陆内变形方式的争论提供了可靠的证据。     

脐带缆螺旋滑移分析及力学性能研究

针对脐带缆内部螺旋层,应用Darboux标架建立螺旋结构空间坐标系,推导弯曲载荷下螺旋结构的局部变形和滑移。考虑螺旋构件间的接触和摩擦作用,建立螺旋结构的受力平衡偏微分方程,并研究螺旋角和摩擦系数对螺旋结构滑移的影响。基于同层螺旋结构本构关系相同假设,将所有螺旋结构力学性能线性叠加,拟合脐带缆整体弯曲刚度。运用建立的理论解析方法,对某双层铠装脐带缆的力学性能进行研究,并与数值模拟结果进行对比验证。对比结果表明,理论解析得到的螺旋滑移结果与数值模拟结果一致,理论解析得到的脐带缆弯曲刚度与数值模拟结果在全滑动阶段比较接近。     

毛乌素沙区1961-2016年降水特征

基于毛乌素沙区10个气象站1961-2016年观测资料，应用Mann-Kendall方法和t检验法对各气象站年降水量进行了突变检验，借助小波分析讨论了各气象站年降水量的周期特征，根据降水量等值线划分结果对整个研究区分区分析了年、季、月和日尺度上的降水变化特征，并在两个时段上分析了季节性降水的差异。结果表明：毛乌素沙区年降水量空间特征差异明显，东部亚区呈上升趋势，中西部亚区呈下降趋势，但变化趋势不显著且无突变发生；降水年内分配不均，干湿季分明，降水集中在5-9月，夏秋季降水占全年降水比重大，季、月和日尺度降水量存在梯度递减变化；年降水量的年际变化过程存在多重时间尺度的自相似结构；近26年的冬春季降水增加显著，但降水波动幅度小于前30年。     

A Revisited Purification of Li for ‘Na Breakthrough’ and its Isotopic Determination by MC‐ICP‐MS

The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l^?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li₂CO₃ (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.     

排酸护肾汤治疗尿酸性肾病30例临床观察

目的：观察排酸护肾汤治疗尿酸性肾病的临床疗效。方法：将60例尿酸性肾病患者随机分为治疗组和对照组各30例，对照组予西医常规治疗，治疗组在对照组治疗的基础上加排酸护肾方超微颗粒治疗，均以2周为1个疗程，治疗3个疗程。观察2组治疗前后的血尿酸（UA）、血肌酐（Scr）、尿素氮（BUN）、尿N-乙酰-β-D-葡萄糖苷酶（UNAG）、尿微量白蛋白（UALB）变化情况，评定综合疗效。结果：总有效率治疗组为90.0%，对照组为70.0%，2组比较，差异有统计学意义（P<0.05）。2组治疗后UA水平均较治疗前降低，差异具有统计学意义（P<0.05），组间比较，差异无统计学意义（P>0.05）；治疗组治疗后BUN、Scr、UNAG、UALB水平均明显下降，且优于对照组治疗后，差异均有统计学意义（P<0.05）。不良反应发生率治疗组及对照组均为3.33%，差异无统计学意义（P>0.05）。结论：排酸护肾汤可有效改善尿酸性肾病患者的临床症状和体征，并可有效降低血UA、Scr、BUN、UNAG、UALB水平，疗效安全确切，值得临床推广应用。     

Petrogenesis of Early Cretaceous hornblende gabbro in Khanka Massif: evidence from geochronology and geochemistry

The authors report zircon U-Pb geochronological,whole-rock geochemical and zircon Lu-Hf isotope data for the hornblende gabbro within the Khanka Massif,with the aim of constraining its formation time and petrogenesis. The zircon U-Pb dating shows that ~(206)Pb/~(238)Pb ages of zircons from the hornblende gabbro range from 120 to 129 Ma,yielding a weighted mean age of 123 ± 2 Ma,i. e.,the Early Cretaceous. The hornblende gabbro has SiO_2 of 44. 77%--46. 58% and belongs to the tholeiitic series on FeO~t/MgO-SiO_2 diagram. It displays a right-inclined REE pattern with( La/Yb)_N ratios of 3. 44 to 4. 42. The trace element spidergram shows that they are enriched in large ion lithophile elements( LILE) such as Rb,Th,U,K and Pb,and depleted in high field strength elements( HFSE) such as Nb,Ta,Ti and P,indicating an affinity to arc igneous rocks.The ε_(Hf)( t) values of zircons vary from -2. 6 to + 3. 9 and Hf model ages( T_(DM1)) range from 622 to 883 Ma.These geochemical characteristics indicate that primary magma of the hornblende gabbro could be derived from partial melting of young mantle material accreted during the Neoproterozoic. Combined with the Early Cretaceous igneous rock assemblages in NE Asia. It is concluded that the hornblende gabbro formed in an active continental margin related to the westward subduction of the Paleo-Pacific Plate beneath the Khanka Massif.     

塔里木盆地苏盖特布拉克剖面寒武系第二统第三阶微生物岩结构类型*

塔里木盆地阿克苏地区寒武系第二统第三阶肖尔布拉克组主要由微生物白云岩组成,代表性的剖面在阿克苏市西南90 km处的苏盖特布拉克。由于成岩作用改造严重,对这套微生物碳酸盐岩的特征和形成环境的认识还存在很多分歧,制约了勘探工作。通过详细野外勘察和室内研究,将肖尔布拉克组微生物岩分为4种结构类型: 凝块结构、纹层结构、砂屑结构和骨架结构。首次对凝块结构和纹层结构进行了亚类型的划分,其中凝块结构可划分为蠕虫状、网状和斑点状3种亚类型,纹层结构可划分为致密纹层、短薄纹层、颗粒纹层以及单纹层、纹层组、复合纹层。肖Ⅰ段—肖Ⅲ段发育凝块石白云岩、凝块—层纹石白云岩和层纹石白云岩,肖Ⅳ段发育凝块石微生物丘,肖V段下部发育网状结构凝块石白云岩,肖V段上部发育砂屑白云岩和肾形菌骨架岩。白云石化作用、溶蚀作用、重结晶作用是改变肖尔布拉克组微生物岩结构最重要的成岩作用,且该组下部比上部遭受了更强的成岩作用改造;微生物岩结构对成岩作用改造的抵抗能力为: 砂屑结构>纹层结构>凝块结构。根据微生物岩结构,推测肖Ⅰ段—肖Ⅲ段形成于潮坪环境,肖Ⅳ段和肖V段下部形成于深水潮下环境,肖V段上部形成于浅水潮下环境。以上成果为认识塔里木盆地肖尔布拉克组微生物岩的平面分布规律和今后开展被成岩作用强烈改造的白云岩型微生物岩的研究提供了一个重要参考。     

岩藻黄素纳米复合物的制备及抗氧化、抗肿瘤活性研究

岩藻黄素是一种脂溶性类胡萝卜素,由于其水溶性差、环境敏感性强,使其应用受到限制。本研究采用有机溶剂浸提、大孔树脂纯化法,从裙带菜中提取高纯度岩藻黄素。通过复凝聚反应制备乳清分离蛋白-岩藻黄素-阿拉伯胶纳米复合物。通过透射电镜观察,纳米复合物呈光滑的球形,粒径约为44nm。红外光谱则表明,岩藻黄素与乳清分离蛋白、阿拉伯树胶发生相互作用,导致联烯键、乙酰基等特征吸收峰被遮蔽。与单一岩藻黄素相比,纳米包封的岩藻黄素具有较好的抗氧化活性稳定性。抗肿瘤实验表明,纳米复合物保留了岩藻黄素抑制HT29细胞增殖的生物活性。